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Submicron γ-LiAlO2 Powder Synthesized from Boehmite(薄姆石合成亚微米γ-偏铝酸锂)

2016年12月22日 19:20  点击:[]

论文名称: Submicron γ-LiAlO2 Powder Synthesized from Boehmite(薄姆石合成亚微米γ-偏铝酸锂)
作者: 程健; 郭烈锦; 许世森; 张瑞云; 李晨
来源出版物: Chinese Journal of Chemical Engineering
年卷期页: 2012,20(4):776—783
收录类型: SCI:006US;WOS:000308845300024和EI
论文简介:  The present study reports a simple,effective and energy-efficient method to prepare γ-LiAlO2 powder as a matrix in a molten carbonate fuel cell(MCFC).In our experiments,aqueous solution based sol-gel technique was used to synthesize γ-LiAlO2.Highly dispersed AlOOH·nH2O and LiOH·H2O aqueous solutions were mixed to form a colloid mixture,which was calcined to synthesize γ-LiAlO2.Thermogravimetric analysis(TGA),X-ray dif-fraction(XRD),and scanning electron microscopy(SEM) were used to study the composition and morphology of the intermediate and final products.The analysis results showed that an intermediate product Li2Al4CO3(OH)12 was produced after the colloid mixture was dried at 80 ℃,and highly purified γ-LiAlO2 powder with fine particle size was resulted from the subsequent calcinations.A single MCFC was assembled with a matrix of the γ-LiAlO2 pow-der.The testing results showed that the matrix performed well in preventing gas leakage.
原文链接: Submicron γ-LiAlO2 Powder Synthesized from Boehmite(薄姆石合成亚微米γ-偏铝酸锂)

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